MSDS

ProCast Art Resin

ProCast Art Hardener

 

Section 1: Identification of the substitution and / or mixture and identification of the company

1.1 Product identifier

Trade name: ProCast Art

Chemical name: a mixture of epoxy resin obtained from A / F bisphenol and epichlorohydrin with an average molecular weight ≤700 and alkyl glycidyl ether (C12- C14). EC number: not applicable Registration number: mixture - it is not subject to registration in accordance with the REACH Regulation 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified applications: for the production of solvent-free coatings Uses advised against: are not known.

1.3 Details of the supplier of the safety data sheet

Supplier: Epideco Ltd

Address: 48 Faraday Road, PL4 0ST, Plymouth, United Kingdom

1.4 Emergency telephone number

998 (fire brigade), 999 (ambulance), 112 (emergency call),

Section 2: Identification of hazards

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 (as amended)

Skin Irrit. 2 H315 - Irritating to skin.

Eye Irrit. 2 H319 - Irritating to eyes.

Skin Sens. 1 H317 - May cause an allergic skin reaction.

Aquatic Chronic 2 H411 - Toxic to aquatic life with long lasting effects.

2.2. Elements of marking

Hazard pictograms and signal word:

ATTENTION

(Pictograms - black symbols on a white background with a red border) Product identifier: ProCast Art includes: Epoxy resin obtained from bisphenol A and epichlorhydrin with an average molecular weight ≤700 (EC No 500-033-5) Reaction product: bisphenol F with epichlorohydrin; an epoxy resin (number average molecular weight ≤ 700) (CAS number 9003-36-5) Alkyl glycidyl ether (C12-14) (index no .: 603-103-00-4)

Hazard statements:

H315 - Irritating to skin.

H319 - Irritating to eyes.

H317 - May cause an allergic skin reaction.

H411 ​​- Toxic to aquatic life with long lasting effects.

Precautionary statements:

P261 Avoid breathing mist / vapors / spray.

P264 Wash hands thoroughly after use.

P280 Wear protective gloves / protective clothing / eye protection / face protection.

P273 Avoid release to the environment.

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Still rinse.

2.3 Other hazards

They are not known.

Section 3: Composition / information on ingredients

3.1 Substances

Not applicable.

3.2. Mixtures

Substance name Identifiers Content

 

Classification according to Regulation (EC) No 1272/2008 (as amended) 1) Mezo-2 reaction mass {[4- (2- {4 - [(oxiran-2-yl) methoxy] phenyl} propan-2- yl) phenoxy] methyl} oxirane and (2RS) -2 - ({4- [2- (4 - {[(2RS) – oxiran-2- yl] methoxy} phenyl) propan-2- yl] phenoxy} methyl) oxirane (An epoxy resin obtained from bisphenol A and epichlorohydrin with medium weight molecular weight ≤700) Registration number: 01-2119456619-26-0013 EC number: 500-033-5 70 ÷ 80 Eye Irrit 2 H319, Skin Irrit 2 H315, Skin Sens 1 H317, Aquatic Chronic 2 H411 The product of the bisphenol F reaction with epichlorohydrin; resin epoxy (average molecular weight ≤ 700) Registration number 01-2119454392-40-xxxx Index number: - CAS number: 9003-36-5 EC number: 500-006-8 5 to 15 Skin Irrit 2 H315, Skin Sens 1 H317, Aquatic Chronic 2 H411 Alkyl glycidyl ether (C12-14) (Mono derivatives [(C12-14-) alkyloxy) methyl] oxirane) index number: 603-103-00-4 CAS number: 68609-97-2 EC number: 271-846-8 10 to 20 Skin Irrit 2 H315 Skin Sens 1 H317,

1) - Full text of abbreviations, symbols, R-phrases and H-phrases - see section 16 of this card.

Section 4: First aid measures

4.1. Description of first aid measures

In contact with skin: remove contaminated clothing and footwear immediately. Wash contaminated skin parts thoroughly with soap and water. If symptoms of irritation / allergy occur, consult a physician. In contact with the eyes: immediately consult a physician. Protect the non-irritated eye, take it out contact lenses. Rinse contaminated eyes thoroughly with water for 10-15 minutes. Avoid strong water jet - the risk of corneal damage. After rinsing, put on sterile - sterile dressing. In the event of ingestion: immediately call a physician, show the packaging or label. Do not call vomiting. Rinse mouth with water and then drink plenty of water. Never give anything to your lips an unconscious person. After inhalation: move the victim to fresh air, keep warm and peace. In case of disturbing ailments, consult a physician. 4.2 Most important symptoms and effects, both acute and delayed In contact with skin: May cause sensitization by skin contact. In contact with eyes: redness, tearing, burning, pain. After ingestion: abdominal pain, nausea.

4.3

Indication of any immediate medical attention and special treatment with the aggrieved party The decision on how to proceed with the rescue should be made by the doctor after careful assessing the condition of the victim. In case of severe poisoning, measures to prevent damage should be provided liver; control heart and circulatory functions. The antidote is missing. Apply symptomatic treatment.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media: dispersed stream of water, foam, carbon dioxide and extinguishing powder. Adapt extinguishing media to materials stored in the environment. Unsuitable extinguishing media: compact streams of water.

5.2. Special hazards arising from the substance or mixture

During combustion can form dangerous vapors and gases containing thermal products decomposition, carbon oxides and soot. Avoid inhalation of combustion products, may pose a threat to health.

5.3. Advice for firefighters

General protection measures typical in case of fire. Do not stay in danger fire zone without proper clothing. Recommended personal protection measures for services rescue: full protective suit, air-insulating breathing apparatus. With waters act as in subsection 6.2. Section 6: Proceeding in the event of an unimpaired release to the environment 6.1 Personal precautions, protective equipment and emergency procedures for persons who are not members of the personnel who eliminate the consequences of a breakdown: limit the access of unauthorized persons to the area of ​​failure until the completion of the relevant cleaning operations. Apply protection measures individual. Avoid contact with skin and eyes. Ensure adequate ventilation. Avoid formation and inhalation of couples For people eliminating the effects of a breakdown: make sure that the removal of failures and its consequences is carried out  only trained staff. Wear protective clothing that is resistant to chemicals and protection individual.

6.2 Environmental precautions

Avoid the formation of vapors. In the event of spillage, steps should be taken to prevent it spreading in the environment - protect against getting into drains, tanks water, rivers, groundwater and soil. Do not use open fire, avoid sparking, eliminate sources of ignition. Notify the appropriate emergency services. Warn others about the occurrence of a threat. Use similar precautions in the event of an extinguishing water (section 5).

6.3 Methods and materials to prevent the spread of contamination and to remove contamination

In case of large spills, collect the liquid that collects, pump out into suitable, tight and labeled containers and transfer for recovery or disposal in accordance with the provisions of the Act about waste. To remove residuals and small amounts of the spilled mixture use sorbent sets, in the absence of them, use diatomaceous earth or sand. An absorbent containing the mixture collect into a suitable leak-proof and labeled waste container and recover or disposal in accordance with the provisions of the Waste Act.

6.4. References to other sections

Waste management of the product - see section 13 of this card. Personal protective equipment - see section 8 of this card. Section 7: Proceedings with substitutes and media and their storage.

7.1 Precautions for safe handling

Work in accordance with the relevant safety and hygiene rules. Avoid eye contactand skin. Take off contaminated clothing and protective equipment before entering the designated areas eating meals. Wash hands with soap and water before breaks and after work. Packaging with keep the mixture tight. Avoid the formation and inhalation of vapors. The rooms should be airy.

7.2. Conditions for safe storage, including information on any reciprocal incompatibilities

Store in original, tightly closed packaging, in dry and airy storage rooms. Keep away from food, feed, dishes on food, in places inaccessible to unauthorized persons. Avoid direct exposure to sunlight, heat and fire. The material is suitable for packaging: drums made of galvanized sheet,

7.3 Specific end use (s)

When processing the mixture, follow the instructions given in this section safety data sheet and instructions that are in force during the process.

Section 8: Accounts: role of exposure / means of individual protection

8.1 Control parameters

The highest permissible concentrations of substances in the work environment in Poland in accordance with with Annex No. 1 to the Regulation of the Minister of Labor and Social Policy of June 6, 2014. on the highest permissible concentrations and intensities of agents harmful to health in work environment (Journal of Laws of 2014, item 817) are: Epoxy resin obtained from bisphenol A and epichlorohydrin of moderate mass molecular weight ≤700 NDS not determined NDSCh not determined

Reaction product bisphenol F with epichlorohydrin (number average molecular weight ≤ 700): NDS not determined NDSCh not determined Derived no-effect (DNEL) levels and predicted no-effect concentrations adverse effects (PNEC)

 

PNEC

Sweet water 0.003 mg / l Morski 0.0003 mg / Wastewater treatment plant 10 mg / Freshwater sediment 0.294 mg / kg s.m. Sediment in sea water 0.0294 mg / kg s.m. Soil 0.237 mg / kg s.m. Periodic release 0.0254 mg / l Alkyl glycidyl ether (C12-14): NDS not determined NDSCh not determined 

DNEL short time; employee; skin; systemic: 17 mg / kg / day

DNEL short time; employee; inhalation; systemic: 29 mg / m3,

DNEL short time; employee; skin; locally: 68 mg / cm3,

DNEL short time; employee; inhalation; locally: 9.8 mg / m3,

DNEL long time; employee; cutaneous, systemic: 3.9 mg / kg bw / day

DNEL long time; employee; inhalation; systemic: 13.8 mg / m3,

DNEL long time; employee; skin; locally: 1.7 mg / cm3,

DNEL long time; employee; inhalation; locally: 0.98 mg / m3,

DNEL short time; consumer; cutaneous, systemic: 10 mg / kg bw / day,

DNEL short time; consumer; inhalation; systemic: 7.6 mg / m3,

DNEL short time; consumer; oral; systemic: 1219 mg / kg bw / day,

DNEL short time; consumer; cutaneous, locally: 40 mg / cm3,

DNEL short time; consumer; inhalation; locally: 2.9 mg / m3,

DNEL long time; consumer; cutaneous, systemic: 2.35 mg / kg / day,

DNEL long time; consumer; inhalation; systemic: 4.1 mg / m3,

DNEL long time; consumer; oral; systemic: 1 mg / kg bw / day,

DNEL long time; consumer; cutaneous, locally: 1 mg / cm3,

DNEL long time; consumer; inhalation; locally: 1.46 mg / m3.

The PNEC values ​​are:

PNEC water (water): 0.0072 mg / L,

PNEC water (sea water): 0.00072 mg / L,

PNEC water (periodic release): 0.072 mg / L,

PNEC sediment (water): 66.77 mg / kg dw,

PNEC sediment (sea water): 6,677 mg / kg dw,

PNEC earth: 80.12 mg / kg dw,

PNEC wastewater treatment plant (STP): 10 mg / L

8.2. Exposure controls

Observe the rules of safety and hygiene. Apply the individual protection measures listed in point 8.2.2. Do not eat, drink or smoke during work. Before break and after work Wash your hands thoroughly with soap and water.

8.2.1. Appropriate technical control measures

Procedures for monitoring concentrations of hazardous components in the air should be applied as well procedures for checking the cleanliness of air in the workplace - if they are available and justified on the given position - in accordance with the appropriate reference methods - standards in force in Poland. The mode, type and frequency of tests and measurements should meet the requirements contained in the regulation Minister of Health of February 2, 2011 on the testing and measurement of agents harmful to health in the work environment (Journal of Laws No. 33, item 166).

8.2.2. Personal protective equipment such as personal protective equipment.

The personal protection equipment used should meet the national requirements contained in Regulation of the Minister of Economy of December 21, 2005 on the essential requirements for personal protective equipment (Journal of Laws No. 259, item 2173) and Regulation (EU) 425/2016. The employer is obliged to provide protection measures appropriate to the activities performed and their maintenance and purification. 

a) Eye or face protection Use safety glasses (goggles) or face protection. b) Skin protection

Hand protection 

Use suitable protective gloves resistant to chemical agents with a minimum thickness 0.4mm tested in accordance with the PN-EN 374 standard - eg nitrile rubber. Body protection Wear protective clothing and safety footwear appropriate to the type of activities performed. Clean contaminated clothing with regular washing. c) Respiratory protection In conditions of good ventilation of the workplace, individual respiratory protection is not required. In case of excessive concentration of fumes, use a mask or half-mask according to EN- 140 with filter type A.

8.2.3. Environmental exposure controls

In order to limit the impact on the environment and human health, the recommendations contained in it must be observed in this safety data sheet. When performing operations with the product in elevated temperatures, use efficient ventilation systems equipped with counteracting devices emission of gases to atmospheric air. Do not contaminate the water with the product or its packaging. Protect against product or packaging getting into sewers, water reservoirs, rivers, groundwater and soil. It is prohibited to recover or dispose of the product, packaging and waste packaging products outside the installations or devices intended for this purpose, meeting the requirements set out in the provisions of the Waste Act.

Section 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties Physical state: low viscosity liquid color: colorless to light yellow smell: characteristic odor threshold: not marked pH value: approx. 6.6 melting / freezing point: not determined glass transition temperature: not determined initial boiling point:> 250 ° C (does not boil) Flash point:> 124 ° C auto-ignition temperature: 405 ° C (998 hPa) evaporation rate: not determined flammability (solid, gas): not applicable upper / lower explosion limit: not determined vapor pressure (20 ° C, 50 ° C): not determined vapor density: not determined density (20 ° C): 1.12 g / cm 3 partition coefficient: n-octanol / water: 3.242 (25 ° C, pH = 7.1) reaction product: bisphenol A with epichlorohydrin 3.77 log POW (20 ° C) alkyl glycidyl ether (C12-14) viscosity (25 ° C): 700 ÷ 900 mPas explosive properties: not determined Oxidizing properties: not applicable solubility: insoluble in water it dissolves in ketones, esters, alcohols and

aromatic hydrocarbons.

9.2 Other information

Lack.

Section 1 0: Stability and food reactivity

10.1 Reactivity

The product reacts with amines, curing amides, strong acids minerals, bases and strong oxidizing agents.

10.2 Chemical stability

With proper use and storage the product is stable.

10.3 Possibility of dangerous reactions

When proceeding according to the purpose and conditions of use and storage there are no recommended conditions. Curing with Lewis acid / base hardeners can be very rapid - with the release of heat.

10.4 Conditions to avoid

Avoid direct sunlight and access of moisture.

10.5 Incompatible materials

Amines, amides that cure the substance, strong oxidizing agents and strong mineral acids or rules.

10.6. Hazardous decomposition products

When properly used and stored, they do not occur - they can occur in the event of a fire (subsection 5.2). Section 1 1: Toxicological information

11.1. Information on toxicological effects

The product was classified using the calculation method, using limit concentrations, given in Part 3, Annex I, CLP Regulation. Epoxy resin obtained from bisphenol A and epichlorhydrin with an average molecular weight ≤700 Acute toxicity: The LD50 values ​​of oral administration and dermal exposure are greater than 15000 and 15000, respectively 23,000 mg / kg for tests carried out before 1982. More recent studies have been carried out at much lower doses without stating the effects associated with the study. LD50 values ​​for oral administration and dermal exposure are higher than the highest doses tested.

- oral route: LD50 rat:> 2000 mg / kg (female)

LD50 rat:> 15000 mg / kg (male)

- dermal route: LD50 rat:> 2000 mg / kg (male / female)

LD50 rabbit:> 3450 mg / kg (female)

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